Photochemical smog is a resultant of the reaction among
[amp_mcq option1=”NO₂, O₃ and peroxyacetyl nitrate in the presence of sunlight” option2=”CO, O₂ and peroxyacetyl nitrate in the presence of sunlight” option3=”CO, CO₂ and NO₂ at low temperature” option4=”high concentration of NO₂, O₃ and CO in the evening” correct=”option1″]
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UPSC IAS – 2013
Photochemical smog is a complex mixture of air pollutants that forms when sunlight reacts with certain chemicals in the atmosphere. Key components and precursors include nitrogen oxides (NOx) and volatile organic compounds (VOCs). The resulting smog contains pollutants like ozone (O₃), peroxyacetyl nitrate (PAN), and aldehydes.
The formation of photochemical smog is driven by sunlight. Nitrogen dioxide (NO₂) is a primary pollutant that photodissociates in sunlight to form nitric oxide (NO) and atomic oxygen (O). This atomic oxygen quickly reacts with molecular oxygen (O₂) to form ozone (O₃). VOCs react with NOx and other atmospheric components in the presence of sunlight to form a variety of secondary pollutants, including PAN. Therefore, NO₂, O₃ (as a product), and PAN (as a product), with sunlight as the driving force, are central to photochemical smog.