My brother play . . . . . . . . me every evening. A. beside B. from C. at D. with

• Beside means “next to” or “alongside.” It would not make sense to say that someone plays beside someone else.
• From means “originating from” or “coming from.” It would not make sense to say that someone plays from someone else.
• At means “in a particular place” or “toward.” It would not make sense to say that someone plays at someone else.

The word “with” is the most logical choice because it indicates that the two people are playing together.