Which one of the following statements is not correct regarding the setting of cement?
The addition of a small percentage of gypsum (CaSO<sub>4</sub>) lengthens the setting period of cement.
According to the colloidal theory, gels of hydrated silicates are formed and when these gels harden, the set cement loses strength.
Tricalcium silicate is responsible for initial setting of cement.
Dicalcium silicate and tricalcium silicate are responsible for the final strength which occurs in about a year.
Answer is Right!
Answer is Wrong!
This question was previously asked in
UPSC CAPF – 2023
The incorrect statement is that according to the colloidal theory, gels harden and the set cement loses strength. When the gels formed during the hydration of cement silicates harden, they form a rigid structure that gives the set cement its strength. Therefore, hardening of gels leads to an *increase* in strength, not a loss.
The setting and hardening of cement are complex processes involving the hydration of its components. The colloidal theory describes the formation of hydration products as gels that eventually solidify. Gypsum (CaSO₄·2H₂O) is added to cement clinker to retard the setting time, preventing flash setting and allowing sufficient time for mixing, placing, and finishing. Tricalcium silicate (C₃S) hydrates relatively quickly and is primarily responsible for the initial set and early strength. Dicalcium silicate (C₂S) hydrates slowly and contributes significantly to the long-term strength gain of concrete.