Which one of the following is a reduction reaction?

Which one of the following is a reduction reaction?

2 Mg (s) + O₂ (g) → 2 MgO (s)
S (s) + O₂ (g) → SO₂ (g)
2 HgO (s) $xrightarrow{heat}$ 2 Hg (l) + O₂ (g)
Mg (s) + S (s) → MgS (s)
This question was previously asked in
UPSC NDA-1 – 2016
The correct answer is C) 2 HgO (s) $\xrightarrow{heat}$ 2 Hg (l) + O₂ (g).
Reduction is a chemical process that involves the gain of electrons, a decrease in oxidation state, gain of hydrogen, or loss of oxygen. In option C, Mercury (Hg) in mercuric oxide (HgO) has an oxidation state of +2. In the product, elemental mercury (Hg) has an oxidation state of 0. The oxidation state of Hg decreases from +2 to 0, which signifies a reduction. Also, the metal oxide is losing oxygen to form the metal, which is a characteristic of reduction processes.
Let’s look at the other options:
A) 2 Mg (s) + O₂ (g) → 2 MgO (s): Mg is oxidized (0 to +2), O₂ is reduced (0 to -2).
B) S (s) + O₂ (g) → SO₂ (g): S is oxidized (0 to +4), O₂ is reduced (0 to -2).
D) Mg (s) + S (s) → MgS (s): Mg is oxidized (0 to +2), S is reduced (0 to -2).
All listed reactions are redox reactions involving both oxidation and reduction. However, option C specifically shows the reduction of a metal cation (Hg²⁺) to its elemental form (Hg⁰) by the loss of oxygen from its compound, making it a clear example of a reduction process relative to the metal. The question asks which *one* is *a* reduction reaction, and while all involve reduction, C best exemplifies the reduction of the stated element (Hg).
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