Two reactants in a flask produce bubbles of gas that turn limewater mi

Two reactants in a flask produce bubbles of gas that turn limewater milky. The gas is

SO₂
NO₂
CO
CO₂
This question was previously asked in
UPSC CISF-AC-EXE – 2019
The gas that turns limewater milky is CO₂.
Limewater is a dilute aqueous solution of calcium hydroxide, Ca(OH)₂. It is a common test reagent for carbon dioxide (CO₂).
When carbon dioxide gas is bubbled through limewater, it reacts with calcium hydroxide to form a precipitate of calcium carbonate (CaCO₃), which is insoluble in water and makes the solution appear milky or cloudy.
The chemical reaction is:
Ca(OH)₂(aq) + CO₂(g) → CaCO₃(s) + H₂O(l)

If excess carbon dioxide is bubbled through the milky solution, the calcium carbonate precipitate reacts further to form soluble calcium bicarbonate, Ca(HCO₃)₂, and the milky appearance disappears.
CaCO₃(s) + CO₂(g) + H₂O(l) → Ca(HCO₃)₂(aq)

Other gases listed:
– SO₂ (Sulfur dioxide) also reacts with limewater, but forms calcium sulfite (CaSO₃), which is also insoluble and causes turbidity. However, the reaction with CO₂ is the most common and characteristic test for CO₂.
– NO₂ (Nitrogen dioxide) is an acidic gas and would react with Ca(OH)₂, but it typically doesn’t produce a milky precipitate with limewater as characteristically as CO₂.
– CO (Carbon monoxide) is a neutral gas and does not react with limewater.

Given the standard chemical tests, turning limewater milky is the definitive test for CO₂.

This reaction is commonly used in experiments to detect the production of carbon dioxide, such as in respiration or combustion.
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