The solution of which one of the following will have pH less than 7?

The solution of which one of the following will have pH less than 7?

NaOH
KCl
FeCl₃
NaCl
This question was previously asked in
UPSC NDA-2 – 2018
The pH of a solution indicates its acidity or alkalinity. A pH less than 7 is acidic, pH equal to 7 is neutral, and pH greater than 7 is alkaline (basic). Let’s analyze the given options:
A) NaOH (Sodium hydroxide) is a strong base. Its solution is alkaline (pH > 7).
B) KCl (Potassium chloride) is a salt formed from a strong acid (HCl) and a strong base (KOH). Its solution is neutral (pH ≈ 7).
C) FeCl₃ (Iron(III) chloride) is a salt formed from a weak base (Fe(OH)₃) and a strong acid (HCl). When dissolved in water, metal ions with high charge density, like Fe³⁺, undergo hydrolysis, reacting with water to produce hydrated metal ions and release H⁺ ions, making the solution acidic: FeCl₃(aq) + 3H₂O(l) ⇌ Fe(OH)₃(s) + 3H⁺(aq) + 3Cl⁻(aq). Therefore, its solution will have a pH less than 7.
D) NaCl (Sodium chloride) is a salt formed from a strong acid (HCl) and a strong base (NaOH). Its solution is neutral (pH ≈ 7).
The pH of a salt solution depends on the strength of the acid and base from which the salt is formed. Salts of strong acid and strong base are neutral, salts of strong acid and weak base are acidic, and salts of weak acid and strong base are alkaline.
Hydrolysis is the reaction of a substance with water. In the case of salts formed from weak acids or bases, the ions can react with water, affecting the pH of the solution. Cations from weak bases and anions from weak acids are the ones that undergo significant hydrolysis.
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