The compound C 6 H 12 O 4 contains

The compound C6H12O4 contains

22 atoms per mole
twice the mass percent of H as compared to the mass percent of C
six times the mass percent of C as compared to the mass percent of H
thrice the mass percent of H as compared to the mass percent of O
This question was previously asked in
UPSC NDA-2 – 2017
We need to analyze the composition of the compound C₆H₁₂O₄ in terms of the relative masses or mass percentages of its constituent elements.
The compound is C₆H₁₂O₄. Using approximate atomic masses (C=12, H=1, O=16):
Mass of C in one molecule = 6 * 12 = 72
Mass of H in one molecule = 12 * 1 = 12
Mass of O in one molecule = 4 * 16 = 64
Total mass of one molecule (or molar mass) = 72 + 12 + 64 = 148.

Let’s evaluate the options:
A) 22 atoms per mole: One molecule contains 6 + 12 + 4 = 22 atoms. One mole contains Avogadro’s number of molecules, so one mole contains 22 * Avogadro’s number of atoms, not just 22 atoms. Incorrect.
B) twice the mass percent of H as compared to the mass percent of C: Mass of C is 72, Mass of H is 12. Is %H = 2 * %C? (12/148)*100% vs 2 * (72/148)*100%. This simplifies to 12 vs 2*72=144. Clearly incorrect. Is %C = 2 * %H? 72 vs 2*12=24. Incorrect.
C) six times the mass percent of C as compared to the mass percent of H: This is poorly phrased but implies a ratio. Let’s check if %C = 6 * %H. Mass of C is 72, Mass of H is 12. 72 = 6 * 12. Yes, the mass of Carbon in the compound is six times the mass of Hydrogen. Since the mass percentages are (mass of element / total mass) * 100%, if Mass of C = 6 * Mass of H, then %C = 6 * %H. This holds true.
D) thrice the mass percent of H as compared to the mass percent of O: Mass of H is 12, Mass of O is 64. Is %O = 3 * %H? 64 vs 3*12=36. Incorrect. Is %H = 3 * %O? 12 vs 3*64. Incorrect.

Option C is the only statement that accurately reflects the mass composition of the compound, interpreting “six times the mass percent of C as compared to the mass percent of H” as the mass percent of C being six times the mass percent of H.

Calculating mass percentages:
%C = (72/148) * 100% ≈ 48.65%
%H = (12/148) * 100% ≈ 8.11%
%O = (64/148) * 100% ≈ 43.24%
Check C: 6 * %H = 6 * 8.11% ≈ 48.66%, which is very close to %C (48.65%).
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