71. When 10 g of calcium carbonate is decomposed completely, then 5.6 g of

When 10 g of calcium carbonate is decomposed completely, then 5.6 g of calcium oxide is formed along with the generation of carbon dioxide. Mass of the carbon dioxide formed is:

[amp_mcq option1=”4.4 g” option2=”5.6 g” option3=”4.6 g” option4=”4.8 g” correct=”option1″]

This question was previously asked in
UPSC Geoscientist – 2020
The mass of the carbon dioxide formed is 4.4 g.
According to the Law of Conservation of Mass, the total mass of the reactants in a chemical reaction is equal to the total mass of the products. In this decomposition reaction, Calcium Carbonate (CaCO₃) decomposes into Calcium Oxide (CaO) and Carbon Dioxide (CO₂).
Given: Mass of reactant (CaCO₃) = 10 g. Mass of one product (CaO) = 5.6 g. Let the mass of the other product (CO₂) be ‘m’. Applying the Law of Conservation of Mass: Mass of CaCO₃ = Mass of CaO + Mass of CO₂. 10 g = 5.6 g + m. m = 10 g – 5.6 g = 4.4 g.

72. The dye in black ink can be separated by the method of:

The dye in black ink can be separated by the method of:

[amp_mcq option1=”evaporation” option2=”fractional distillation” option3=”dialysis” option4=”chromatography” correct=”option4″]

This question was previously asked in
UPSC Geoscientist – 2020
The dye in black ink can be separated by the method of chromatography.
Black ink is typically a mixture of several different coloured dyes. Chromatography is a technique used to separate components of a mixture based on their differential partitioning between a stationary phase and a mobile phase. Different dyes in the ink travel at different rates through the stationary phase (like paper), causing them to separate.
Evaporation is used to separate a soluble solid from a liquid. Fractional distillation separates liquids with different boiling points. Dialysis separates particles based on size using a semipermeable membrane. Chromatography is the standard method for separating different coloured dyes in ink.

73. Which one of the following is NOT an example of colloids?

Which one of the following is NOT an example of colloids?

[amp_mcq option1=”Milk” option2=”Jelly” option3=”Tincture of iodine” option4=”Fog” correct=”option3″]

This question was previously asked in
UPSC Geoscientist – 2020
Tincture of iodine is NOT an example of a colloid; it is a true solution.
A colloid is a heterogeneous mixture where the solute particles are dispersed uniformly throughout the solvent. The particle size in colloids is typically between 1 nm and 1000 nm. True solutions have particle sizes smaller than 1 nm.
Milk is an emulsion (liquid dispersed in liquid). Jelly is a gel (solid dispersed in liquid). Fog is an aerosol (liquid dispersed in gas). All of these are types of colloids. Tincture of iodine is a solution of iodine in alcohol, where iodine dissolves completely forming a homogeneous mixture at the molecular level.

74. Number of states of matter known so far is:

Number of states of matter known so far is:

[amp_mcq option1=”3″ option2=”4″ option3=”5″ option4=”6″ correct=”option3″]

This question was previously asked in
UPSC Geoscientist – 2020
The number of states of matter commonly known and taught in a general science context is considered to be 5.
The three classical states of matter are Solid, Liquid, and Gas. Beyond these, Plasma is widely recognized as a fourth state, and the Bose-Einstein Condensate (BEC) is considered a fifth state.
Plasma is an ionized gas existing at high temperatures. BEC is formed at temperatures near absolute zero. Other states of matter exist under extreme conditions (e.g., neutron-degenerate matter), but 5 is the most common answer when these options are presented.

75. Which one of the following statements is correct about camphor and amm

Which one of the following statements is correct about camphor and ammonium chloride?

[amp_mcq option1=”Both of them are inorganic compounds” option2=”Both of them are organic compounds” option3=”Both of them undergo sublimation” option4=”Camphor is an element but ammonium chloride is a compound” correct=”option3″]

This question was previously asked in
UPSC Geoscientist – 2020
Both camphor and ammonium chloride undergo sublimation.
Sublimation is the process where a substance transitions directly from the solid to the gas state, without passing through the liquid state. Both camphor and ammonium chloride exhibit this property under appropriate conditions.
Camphor (C₁₀H₁₆O) is an organic compound. Ammonium chloride (NH₄Cl) is an inorganic compound. Therefore, statements A, B, and D are incorrect. Camphor sublimes readily at room temperature, while ammonium chloride sublimes upon heating.

76. At a given temperature and pressure, the force of attraction among the

At a given temperature and pressure, the force of attraction among the molecules will be highest in case of:

[amp_mcq option1=”helium” option2=”sugar” option3=”water” option4=”carbon tetrachloride” correct=”option2″]

This question was previously asked in
UPSC Geoscientist – 2020
At a given temperature and pressure, the state of matter (solid, liquid, gas) is determined by the strength of the intermolecular forces compared to the thermal energy of the molecules. Solids have the strongest intermolecular forces, holding molecules in fixed positions. Liquids have weaker forces than solids, allowing molecules to move past each other but still keeping them relatively close. Gases have very weak forces, allowing molecules to move freely and far apart. At room temperature and pressure: Helium is a gas, Water and Carbon tetrachloride are liquids, and Sugar is a solid. Therefore, sugar, being in a solid state, will have the highest force of attraction among its molecules compared to the liquids and the gas listed.
The state of matter (solid, liquid, gas) reflects the strength of intermolecular forces. Solids have the strongest forces, liquids have intermediate forces, and gases have the weakest forces. Sugar is a solid at room temperature and pressure, while the other substances are liquids or gases.
Intermolecular forces include London dispersion forces, dipole-dipole forces, and hydrogen bonding. Sugar molecules (like sucrose) are polar and can form extensive hydrogen bonds, in addition to other forces, resulting in a strong lattice structure in the solid state. Helium, a noble gas, only has very weak London dispersion forces. Water has strong hydrogen bonding, but it’s a liquid at room temperature. Carbon tetrachloride is a nonpolar molecule with only London dispersion forces, existing as a liquid.

77. In which of the following colloids is the dispersing medium a liquid ?

In which of the following colloids is the dispersing medium a liquid ?

[amp_mcq option1=”Mist” option2=”Foam” option3=”Jelly” option4=”Shaving cream” correct=”option3″]

This question was previously asked in
UPSC CDS-2 – 2024
A colloid consists of a dispersed phase (the substance distributed) and a dispersing medium (the substance in which the dispersed phase is distributed). In shaving cream, gas bubbles are dispersed within a liquid medium, forming a foam. Therefore, the dispersing medium in shaving cream is a liquid.
– Colloids are mixtures with particles intermediate in size between solutions and suspensions.
– Identifying the dispersed phase and dispersing medium is key to classifying colloids.
– Mist is an aerosol where liquid droplets are dispersed in a gas (air). The dispersing medium is gas.
– Jelly is a gel where a liquid is dispersed in a solid network. The dispersing medium is effectively solid.
– Foam is a colloid where gas is dispersed in a liquid (liquid foam) or solid (solid foam). While ‘Foam’ could be ambiguous, Shaving cream is a specific example of a liquid foam.

78. In which one of the following cases do both physical and chemical chan

In which one of the following cases do both physical and chemical changes take place?

[amp_mcq option1=”Burning of candle” option2=”Freezing of water” option3=”Cooking of food” option4=”Rusting of iron” correct=”option1″]

This question was previously asked in
UPSC CDS-2 – 2023
A physical change involves a change in the form or appearance of a substance but not its chemical composition (e.g., changes of state). A chemical change involves a change in the chemical composition of a substance, resulting in the formation of new substances (e.g., combustion, rusting).
In the burning of a candle, the wax melts (physical change) and turns into liquid. This liquid wax is then drawn up the wick, vaporizes, and reacts with oxygen in the air (combustion), producing carbon dioxide, water vapor, heat, and light (chemical change). Thus, both physical (melting/vaporization of wax) and chemical (combustion of wax vapor) changes occur simultaneously as the candle burns.
Freezing of water is purely a physical change (liquid to solid). Rusting of iron is a chemical change (iron reacts with oxygen and water). Cooking of food involves primarily chemical changes in the food components (e.g., protein denaturation, starch gelatinization), although physical processes like boiling water might be involved as a heating method.

79. Which among the following methods is used to separate the constituents

Which among the following methods is used to separate the constituents present in a compound ?

[amp_mcq option1=”Electrochemical method” option2=”Heating method” option3=”Fractional distillation” option4=”Decomposition followed by ion exchange” correct=”option1″]

This question was previously asked in
UPSC CDS-2 – 2023
To separate the constituents (elements) present in a compound, chemical bonds must be broken. This process is called decomposition. Decomposition requires energy and can be achieved through various methods, including using electricity (electrolysis), heat (thermal decomposition), or light (photolysis). Electrochemical methods, such as electrolysis, are used to decompose certain compounds (like water or molten salts) into their constituent elements by passing an electric current through them.
Separating constituents of a compound involves breaking chemical bonds, which is a chemical process (decomposition). This is distinct from separating components of a mixture, which involves physical methods like distillation, filtration, etc.
Option B, Heating method (thermal decomposition), is also a valid method to decompose some compounds, but not all. Option C, Fractional distillation, is a technique used to separate liquids with different boiling points from a *mixture*, not to separate elements bonded within a compound. Option D, Decomposition followed by ion exchange, is a specific process for separating ions after decomposition, but the decomposition itself is the key step in breaking down the compound. Among the given options, Electrochemical method represents a fundamental way to chemically decompose compounds into their constituents.

80. Employing Chromatography, one cannot separate

Employing Chromatography, one cannot separate

[amp_mcq option1=”radio-isotopes” option2=”colours from a dye” option3=”pigments from a natural colour” option4=”drugs from blood” correct=”option1″]

This question was previously asked in
UPSC CDS-2 – 2019
Chromatography is a technique used to separate components of a mixture based on their differential partitioning between a stationary phase and a mobile phase. It is highly effective for separating substances like colours from a dye, pigments from a natural colour, or components like drugs from complex biological matrices such as blood.
Radio-isotopes are different forms of the same element, differing only in the number of neutrons (and thus mass) but having the same chemical properties. Chromatography separates based primarily on physical or chemical interactions that relate to solubility, adsorption, volatility, size, or charge. Since isotopes of an element have virtually identical chemical behaviour, chromatography is generally not a suitable method for separating radio-isotopes. Techniques like mass spectrometry, gas diffusion, or centrifugation are typically used for isotope separation based on mass differences.
While certain specialized chromatographic techniques might theoretically distinguish between isotopes based on subtle differences in physical properties or reaction kinetics, standard chromatography methods are not designed for or capable of effective radio-isotope separation. The question likely refers to standard chromatographic applications.

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