The correct answer is (b).
Suppose $x, y, z$ are three positive integers such that $x < yz$ and $xyz = 13$. We can factor $13$ as $13 = 1 \cdot 13 = 3 \cdot 4 = 6 \cdot 2$. Therefore, we can choose $x, y, z$ to be any of the following ordered triples:
- $(1, 13)$
- $(3, 4)$
- $(6, 2)$
Since there are three possible solutions, $S = 13$ yields more than one solution to the equation $x + y + z = S$.
For the other options, we can see that there is only one solution to the equation $x + y + z = S$ for each value of $S$.
- For $S = 4$, the only solution is $(1, 1, 2)$.
- For $S = 15$, the only solution is $(3, 5, 3)$.
- For $S = 16$, the only solution is $(4, 4, 4)$.