Match List I with List II and select the correct answer using the code

Match List I with List II and select the correct answer using the code given below the Lists :

List I
(Element)
List II
(Highest Valency)
A. Sulfur1. Five
B. Phosphorous2. Six
C. Lead3. Two
D. Silver4. Four

Code :

ABCD
(a)2413
(b)2143
(c)3142
(d)3412
2, 4, 1, 3
2, 1, 4, 3
3, 1, 4, 2
3, 4, 1, 2
This question was previously asked in
UPSC NDA-2 – 2016
The correct match is A-2, B-1, C-4, D-3.
The highest common valency (or oxidation state) for the elements are:
– Sulfur (S): Can exhibit +6 (e.g., in sulfates), so highest valency is Six (2).
– Phosphorus (P): Can exhibit +5 (e.g., in phosphates), so highest valency is Five (1).
– Lead (Pb): Can exhibit +4 (e.g., PbO₂), so highest valency is Four (4).
– Silver (Ag): The most common valency/oxidation state is +1. While higher, unstable oxidation states exist, +1 is the standard. The option provides ‘Two’ (3) as the highest valency for Silver. Assuming this option set is intended, the pairings match option B for A, B, and C.
Based on standard chemistry, the highest common valency for Silver is 1. However, matching the provided options, A-2, B-1, C-4 align with common understanding, leading to option B being the most probable intended answer despite the inaccuracy regarding Silver’s listed highest valency.