Manganese is extracted from Manganese dioxide by reaction with Alumini

Manganese is extracted from Manganese dioxide by reaction with Aluminium as described by the following unbalanced chemical equation :
MnO₂(s) + Al (s) → Mn (l) + Al₂O₃ (s)
The number of moles of Al (s) required to form one mole of Mn from its oxide is

1
0.75
1.33
2
This question was previously asked in
UPSC CISF-AC-EXE – 2020
The unbalanced chemical equation is MnO₂(s) + Al (s) → Mn (l) + Al₂O₃ (s). To determine the moles of Al required to form one mole of Mn, we first need to balance the equation.
Balancing the oxygen atoms (2 on the left, 3 on the right), we find the least common multiple is 6. Multiply MnO₂ by 3 and Al₂O₃ by 2:
3 MnO₂(s) + Al (s) → Mn (l) + 2 Al₂O₃ (s)
Now, balance the aluminium atoms (1 on the left, 4 on the right). Multiply Al by 4:
3 MnO₂(s) + 4 Al (s) → Mn (l) + 2 Al₂O₃ (s)
Finally, balance the manganese atoms (3 on the left, 1 on the right). Multiply Mn by 3:
3 MnO₂(s) + 4 Al (s) → 3 Mn (l) + 2 Al₂O₃ (s)
The balanced equation is 3 MnO₂(s) + 4 Al (s) → 3 Mn (l) + 2 Al₂O₃ (s).
According to the balanced equation, 4 moles of Al react to produce 3 moles of Mn. To produce 1 mole of Mn, the number of moles of Al required is (4 moles Al / 3 moles Mn) * 1 mole Mn = 4/3 moles Al.
The question requires balancing the given chemical equation and then using stoichiometry to find the mole ratio between reactants and products. The ratio of Al to Mn in the balanced equation is 4:3.
This reaction is a type of redox reaction, specifically a thermite reaction where a metal oxide is reduced by a more reactive metal (Aluminium). Aluminium is a strong reducing agent. The value 4/3 is approximately 1.333…