If two miscible liquids of same volume but different densities P 1 an

If two miscible liquids of same volume but different densities P1 and P2 are mixed, then the density of the mixture is given by

(P<sub>1</sub> + P<sub>2</sub>) / 2
2P<sub>1</sub>P<sub>2</sub> / (P<sub>1</sub> + P<sub>2</sub>)
2P<sub>1</sub>P<sub>2</sub> / (P<sub>1</sub> - P<sub>2</sub>)
P<sub>1</sub>P<sub>2</sub> / (P<sub>1</sub> + P<sub>2</sub>)
This question was previously asked in
UPSC CDS-2 – 2018
Let V be the volume of each liquid. The total volume of the mixture is V_total = V + V = 2V.
The mass of the first liquid is m₁ = density × volume = P₁V.
The mass of the second liquid is m₂ = density × volume = P₂V.
The total mass of the mixture is m_total = m₁ + m₂ = P₁V + P₂V = (P₁ + P₂)V.
The density of the mixture is ρ_mixture = m_total / V_total = (P₁ + P₂)V / (2V) = (P₁ + P₂) / 2.
This formula is valid when equal volumes of two miscible liquids are mixed.
– Density is mass per unit volume.
– When mixing, total mass is the sum of individual masses, and total volume is the sum of individual volumes (assuming no volume change upon mixing, which is typical for miscible liquids unless otherwise specified).
– The calculation is based on the given condition that the liquids have the ‘same volume’.
If two miscible liquids of *same mass* m but different densities P₁ and P₂ are mixed, the volume of the first liquid is V₁ = m/P₁, and the volume of the second liquid is V₂ = m/P₂. The total mass is 2m, and the total volume is V₁ + V₂ = m/P₁ + m/P₂ = m(P₁ + P₂)/(P₁P₂). The density of the mixture would be (2m) / [m(P₁ + P₂)/(P₁P₂)] = 2P₁P₂ / (P₁ + P₂), which is option B. The question specifies ‘same volume’, not ‘same mass’.
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