The correct answer is: Copper at cathode and oxygen at anode.
When an aqueous solution of copper sulphate is electrolysed using copper electrodes, the following reaction occurs at the cathode:
$Cu^{2+} + 2e^- \to Cu$
This means that copper ions are reduced to copper metal at the cathode.
The following reaction occurs at the anode:
$2H_2O \to O_2 + 4H^+ + 4e^-$
This means that water is oxidised to oxygen gas and hydrogen ions at the anode.
The overall reaction is:
$Cu^{2+} + 2H_2O \to Cu + O_2 + 4H^+$
This reaction shows that copper is deposited at the cathode and oxygen gas is evolved at the anode.
The other options are incorrect because:
- Option B is incorrect because copper is deposited at the cathode, not the anode.
- Option C is incorrect because the anodes do not dissolve to give copper.
- Option D is incorrect because hydrogen gas is not produced at the cathode.