Choose the pair in which the words are differently related from the rest.

Pyroheliometer : Radiation
Calorimeter : Heat
Planimeter : Area
Barometer : Humidity

The correct answer is D. Barometer : Humidity.

A pyroheliometer is an instrument used to measure solar radiation. A calorimeter is an instrument used to measure heat. A planimeter is an instrument used to measure area. A barometer is an instrument used to measure air pressure.

Humidity is the amount of water vapor in the air. It is not measured by a barometer.

The other three pairs are all related in that the first word is an instrument that measures the second word.

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