Bihar’s largest industrial hub is located in and around the city of:

Patna
Muzaffarpur
Bhagalpur
Gaya

The correct answer is Patna.

Patna is the capital of Bihar and the largest city in the state. It is located on the banks of the Ganges River and is a major transportation hub. Patna is also a major industrial center, with industries such as textiles, engineering, and pharmaceuticals.

Muzaffarpur is the second largest city in Bihar and is located in the north-central part of the state. It is a major agricultural center and is also home to a number of industries, including textiles, engineering, and food processing.

Bhagalpur is the third largest city in Bihar and is located in the south-central part of the state. It is a major industrial center, with industries such as textiles, engineering, and chemicals.

Gaya is the fourth largest city in Bihar and is located in the south-eastern part of the state. It is a major religious center and is also home to a number of industries, including textiles, engineering, and food processing.

In conclusion, Patna is the largest industrial hub in Bihar. It is a major transportation hub and is home to a number of industries, including textiles, engineering, and pharmaceuticals.