An element has an atomic number of 16. What is the principal quantum number (n) of its outermost electrons ?
1
2
3
4
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UPSC CISF-AC-EXE – 2020
An element with atomic number 16 is Sulfur (S). To find the principal quantum number (n) of its outermost electrons, we need to write its electron configuration. The atomic number represents the number of protons and, in a neutral atom, the number of electrons. So, Sulfur has 16 electrons. The electron configuration is filled according to the Aufbau principle, Hund’s rule, and the Pauli exclusion principle.
Filling order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, …
Electrons:
1s² (2 electrons)
2s² (2 electrons)
2p⁶ (6 electrons) – total 2+2+6 = 10 electrons
3s² (2 electrons) – total 10+2 = 12 electrons
3p⁴ (4 electrons) – total 12+4 = 16 electrons
The electron configuration is 1s² 2s² 2p⁶ 3s² 3p⁴. The outermost electrons are those in the highest principal energy level, which is n=3 in this case (3s and 3p orbitals).
The principal quantum number (n) of the outermost electrons corresponds to the highest energy level occupied by electrons in the atom’s electron configuration. For Sulfur (atomic number 16), the configuration is 1s² 2s² 2p⁶ 3s² 3p⁴, so the outermost electrons are in the n=3 level.