In which of the following pairs are the ions isoelectronic ?

In which of the following pairs are the ions isoelectronic ?

Mg$^{2+}$, Ar
Na$^{+}$, O$^{2-}$
Al$^{3+}$, Cl$^{-}$
K$^{+}$, Ne
This question was previously asked in
UPSC NDA-1 – 2019
The pair Na⁺ and O²⁻ are isoelectronic.
Isoelectronic species are atoms or ions that have the same number of electrons. Let’s check the electron count for each species:
– Mg²⁺: Magnesium (Mg) has atomic number 12, so it has 12 electrons. Mg²⁺ has lost 2 electrons, so it has 10 electrons.
– Ar: Argon (Ar) has atomic number 18, so it has 18 electrons.
– Na⁺: Sodium (Na) has atomic number 11, so it has 11 electrons. Na⁺ has lost 1 electron, so it has 10 electrons.
– O²⁻: Oxygen (O) has atomic number 8, so it has 8 electrons. O²⁻ has gained 2 electrons, so it has 10 electrons.
– Al³⁺: Aluminum (Al) has atomic number 13, so it has 13 electrons. Al³⁺ has lost 3 electrons, so it has 10 electrons.
– Cl⁻: Chlorine (Cl) has atomic number 17, so it has 17 electrons. Cl⁻ has gained 1 electron, so it has 18 electrons.
– K⁺: Potassium (K) has atomic number 19, so it has 19 electrons. K⁺ has lost 1 electron, so it has 18 electrons.
– Ne: Neon (Ne) has atomic number 10, so it has 10 electrons.

Comparing the pairs:
A) Mg²⁺ (10e⁻), Ar (18e⁻) – Not isoelectronic.
B) Na⁺ (10e⁻), O²⁻ (10e⁻) – Isoelectronic.
C) Al³⁺ (10e⁻), Cl⁻ (18e⁻) – Not isoelectronic.
D) K⁺ (18e⁻), Ne (10e⁻) – Not isoelectronic.

Many ions of elements close to noble gases are isoelectronic with the nearest noble gas. For example, Na⁺, Mg²⁺, Al³⁺, O²⁻, F⁻ are all isoelectronic with Neon (10 electrons). K⁺, Ca²⁺, S²⁻, Cl⁻ are all isoelectronic with Argon (18 electrons). Isoelectronic species often have similar chemical properties related to their electron configuration.